Your loads should be balanced as well as possible between the two 50 amp legs. What I believe you are suggesting is to take one leg of the coach's 50 amp circuit and run it directly to the inverter than run the inverter out back to the power than leg. The disadvantage to this approach is you would either have things you don't want powered off the inverter, such as electric heaters and air conditioners OR you would have to reshuffle the load and put all of those items on the opposite leg and that would not be good for 'normal' load balancing.
I have not looked at the circuit on the charger/converter (very hard to access on my coach) but I would doubt that you could disable the charger component without disabling the converter component also.
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